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The command "ipconfig /all" is utilized in Windows operating systems to provide comprehensive details regarding the network configuration of Network Interface Cards (NICs). When executed, this command presents a detailed view of various network settings, including the IP address, subnet mask, default gateway, DNS servers, and MAC address for each NIC installed on the system.

This detailed output is critical for network troubleshooting and configuration management, allowing an investigator or administrator to identify how the computer is connected to the network and to verify whether the settings align with the expected configurations. The command also helps in diagnosing network issues by providing IP configuration information necessary for understanding connectivity issues.

In contrast, the other commands serve different purposes. "netstat" primarily displays active network connections and routing tables, "tasklist" provides a list of currently running processes, and "net session" is used to view active sessions on a server but does not focus on network configuration details of NICs. This distinction highlights why "ipconfig /all" is the most relevant command for obtaining detailed network configuration information.